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Thermal Expansion case study

Thermal Expansion case study

Introduction


When heat is applied to most materials, expansion occurs in all directions. Conversely, if heat energy is removed from a material (i.e. the material is cooled) contraction occurs in all directions. The effects of expansion and contraction each depend on the change of temperature of the material.






Coefficient of Linear Expansion

The amount by which unit length of a material expands when the temperature is raised one degree is called the coefficient of linear expansion of the material and is represented by (𝛼)
the coefficient of linear expansion  means that a 1 m long material expands by (dl ) m if its temperature is increased by 1 K (or 1°C).
If a material, initially of length l1 and at a temperature of t1 and having a coefficient of linear expansion 𝛼, has its temperature increased to t2, then the new length l2 of the material is given by:
l2 = l1 [1 + 𝛼.(t2 − t1)]

Coefficient of Superficial Expansion
The amount by which unit area of a material increases when the temperature is raised by one degree is called the coefficient of superficial (i.e. area) expansion and is represented by 𝛽
If a material having an initial surface area A1 at temperature t1 and having a coefficient of superficial expansion  𝛽, has its temperature increased to t2, then the new surface area A2 of the material is given by:
A2 = A1 [1 + 𝛽.(t2 − t1)]

It may be shown that the coefficient of superficial expansion is twice the coefficient of linear expansion, i.e. 𝛽= 2𝛼 , to a very close approximation.


Coefficient of Cubic Expansion

The amount by which unit volume of a material increases for a one degree rise of temperature is called the coefficient of cubic (or volumetric) expansion and is represented by 𝛄
If a material having an initial volume V1 at temperature t1 and having a coefficient of cubic expansion  𝛄, has its temperature raised to t2, then the new volume V2 of the material is given by:
V2 = V1[1+  𝛄.(t2 − t1)]

It may be shown that the coefficient of cubic expansion is three times the coefficient of linear expansion, i.e.𝛄 = 3 𝛼  , to a very close approximation.

A liquid has no definite shape and only its cubic or volumetric expansion need be considered. Thus with expansions in liquids

Practical Applications of Thermal Expansion

Some practical applications where expansion and contraction of solid materials
must be allowed for include:
(i) Overhead electrical transmission lines are hung so that they are slack in summer, otherwise their contraction in winter may snap the conductors or bring down pylons.
(ii) Gaps need to be left in lengths of railway lines to prevent buckling in hot weather (except where these are continuously welded).
(iii) Ends of large bridges are often supported on rollers to allow them to expand and contract freely.
(iv) Fitting a metal collar to a shaft or a steel tyre to a wheel is often achieved by first heating them so that they expand, fitting them in position, and then cooling them so that the contraction holds them firmly in place; this is known as a ‘shrink-fit’. By a similar method hot rivets are used for joining metal sheets.
(v) The amount of expansion varies with different materials. Figure (a) shows a bimetallic strip at room temperature (i.e. two different strips of metal riveted together). When heated, brass expands more than steel, and since the two metals are riveted together the bimetallic strip is forced into
an arc as shown in Figure (b). Such a movement can be arranged to make or break an electric circuit and bimetallic strips are used, in particular, in thermostats (which are temperature-operated switches) used to control central heating systems, cookers, refrigerators, toasters, irons, hot water and alarm systems.

(vi) Motor engines use the rapid expansion of heated gases to force a piston to move.

(vii) Designers must predict, and allow for, the expansion of steel pipes in a steam-raising plant so as to avoid damage and consequent danger to health.


Expansion and Contraction of Water

Water is a liquid that at low temperature displays an unusual effect. If cooled, contraction occurs until, at about 4°C, the volume is at a minimum. As the temperature is further decreased from 4°C to 0°C expansion occurs, i.e. the volume increases. When ice is formed, considerable expansion occurs and it is this expansion that often causes frozen water pipes to burst.
A practical application of the expansion of a liquid is with thermometers, where the expansion of a liquid, such as mercury or alcohol, is used to measure temperature.





Thermal expansion coefficients

Linear temperature expansion coefficients for aluminum, copper, glass, iron and other common materials
When an object is heated or cooled, its length change by an amount proportional to the original length and the change in temperature
Thermal expansion coefficients for some common materials



Product
Linear Temperature ExpansionCoefficient
- α -
10-6 (m/(m K))
ABS (Acrylonitrile butadiene styrene) thermoplastic
72 - 108
40 - 60
ABS -glass fiber-reinforced
31
17.2
Acetals
85 - 110
47.2 - 61.1
Acetal - glass fiber-reinforced
39
21.7
Acrylic
68 - 75
37.8 - 41.7
Alumina (aluminium oxide, Al2O3)
8.1
4.5
Aluminum
21 - 24
11.7 - 13.3
Aluminum nitride
5.3
2.94
Amber
50 - 60
27.8 - 33.3
Antimony
9 - 11
5 - 6.11
Arsenic
4.7
2.61
Bakelite, bleached
22
12.2
Barium
20.6
11.4
Barium ferrite
10
5.56
Benzocyclobutene
42
23.3
Beryllium
12
6.67
Bismuth
13 - 13.5
7.22 - 7.5
Brass
18 - 19
10 - 10.6
Brick masonry
5
2.78
Bronze
17.5 - 18
9.72 - 10
Cadmium
30
16.7
Calcium
22.3
12.4
Cast Iron Gray
10.8
6
Caoutchouc
66 - 69
36.7 - 38.3
Celluloid
100
55.6
Cellulose acetate (CA)
130
72.2
Cellulose acetate butynate (CAB)
96 - 171
53.3 - 95
Cellulose nitrate (CN)
80 - 120
44.4 - 66.7
Cement, Portland
11
6.11
Cerium
5.2
2.89
Chlorinated polyether
80
44.4
Chlorinated polyvinylchloride (CPVC)
63 - 66
35 - 36.7
Chromium
6 - 7
3.33 - 3.89
Clay tile structure
5.9
3.28
Cobalt
12
6.67
Concrete
13 - 14
7.22 - 7.78
Concrete structure
9.8
5.44
Constantan
15.2 - 18.8
8.44 - 10.4
Copper
16 - 16.7
8.89 - 9.28
Copper, Beryllium 25
17.8
9.89
Corundum, sintered
6.5
3.61
Cupronickel 30%
16.2
9
Diamond (Carbon)
1.1 - 1.3
0.61 - 0.72
Duralumin
23
12.8
Dysprosium
9.9
5.5
Ebonite
70
38.9
Epoxy, cast resins & compounds, unfilled
45 - 65
25 - 36.1
Epoxy - glass fiber reinforced
36
20
Erbium
12.2
6.78
Ethylene ethyl acrylate (EEA)
205
114
Ethylene vinyl acetate (EVA)
180
100
Europium
35
19.4
Fluoroethylene propylene (FEP)
135
75
Fluorspar, CaF2
19.5
10.8
Gadolinium
9
5
Germanium
6.1
3.39
German silver
18.4
10.2
Glass, hard
5.9
3.28
Glass, Pyrex
4.0
2.22
Glass, plate
9.0
5
Gold
14.2
7.89
Gold - copper
15.5
8.61
Gold - platinum
15.2
8.44
Granite
7.9 - 8.4
4.39 - 4.67
Graphite, pure (Carbon)
4 -8
2.22
Gunmetal
18
10
Gutta percha
198
110
Hafnium
5.9
3.28
Hard alloy K20
6
3.33
Hastelloy C
11.3
6.28
Holmium
11.2
6.22
Ice, 0oC water
51
28.3
Inconel
11.5 - 12.6
6.39 - 7
Indium
33
18.3
Invar
1.5
0.83
Iridium
6.4
3.56
Iron, pure
12.0
6.67
Iron, cast
10.4 - 11
5.78 - 6.11
Iron, forged
11.3
6.28
Kapton
20
11.1
Lanthanum
12.1
6.72
Lead
29
16.1
Limestone
8
4.44
Lithium
46
25.6
Lutetium
9.9
5.5
Macor
9.3
5.17
Magnalium
23.8
13.2
Magnesium
25 - 26.9
13.9 - 14.9
Manganese
22
12.2
Manganin
18.1
10.1
Marble
5.5 - 14.1
3.06 - 7.83
Masonry, brick
4.7 - 9.0
2.61 - 5
Mercury
61
33.9
Mica
3
1.67
Molybdenum
5
2.78
Monel metal
13.5
7.5
Mortar
7.3 - 13.5
4.06 - 7.5
Neodymium
9.6
5.33
Nickel
13.0
7.22
Niobium (Columbium)
7
3.89
Nylon, general purpose
50 - 90
27.8 - 50
Nylon, glass fiber reinforced
23
12.8
Nylon, Type 11, molding and extruding compound
100
55.6
Nylon, Type 12, molding and extruding compound
80.5
44.7
Nylon, Type 6, cast
85
47.2
Nylon, Type 6/6, molding compound
80
44.4
Oak, perpendicular to the grain
54
30
Osmium
5 - 6
2.78 - 3.33
Palladium
11.8
6.56
Paraffin
106 - 480
58.9 - 267
Phenolic resin without fillers
60 - 80
33.3 - 44.4
Phosphor bronze
16.7
9.28
Plaster
17
9.44
Plastics
40 - 120
22.2 - 66.7
Platinum
9
5
Plutonium
47 - 54
26.1 - 30
Polyacrylonitrile
70
38.9
Polyallomer
92
51.1
Polyamide (PA)
110
61.1
Polybutylene (PB)
130 - 139
72.2 - 77.2
Polycarbonate (PC)
65 - 70
36.1 - 38.9
Polycarbonate - glass fiber-reinforced
21.5
11.9
Polyester
124
68.9
Polyester - glass fiber-reinforced
25
13.9
Polyethylene (PE)
108 - 200
60 - 111
Polyethylene (PE) - High Molecular Weight
108
60
Polyethylene terephthalate (PET)
59.4
33
Polyphenylene
54
30
Polyphenylene - glass fiber-reinforced
36
20
Polypropylene (PP), unfilled
72 - 90
40 - 50
Polypropylene - glass fiber-reinforced
32
17.8
Polystyrene (PS)
70
38.9
Polysulfone (PSO)
55 - 60
30.6 - 33.3
Polytetrafluorethylene (PTFE)
112 - 135
62.2 - 75
Polyurethane (PUR), rigid
57.6
32
Polyvinyl chloride (PVC)
54 - 110
30 - 61.1
Polyvinylidene fluoride (PVDF)
128 - 140
71.1 - 77.8
Porcelain, Industrial
4
2.22
Potassium
83
46.1
Praseodymium
6.7
3.72
Promethium
11
6.11
Quartz, mineral
8 - 14
4.44 - 7.78
Quartz, fused
0.55
0.31
Rhenium
6.7
3.72
Rhodium
8
4.44
Rock salt
40.4
22.4
Rubber, hard
80
44.4
Ruthenium
9.1
5.06
Samarium
12.7
7.06
Sandstone
11.6
6.44
Sapphire
5.3
2.94
Scandium
10.2
5.67
Selenium
37
20.6
Silicon
3 - 5
1.67 - 2.78
Silicon Carbide
2.77
1.54
Silver
19 - 19.7
10.6 - 10.9
Sitall
0.15
0.0833
Slate
10
5.56
Sodium
70
38.9
Solder lead - tin, 50% - 50%
25
13.9
Speculum metal
19.3
10.7
Steatite
8.5
4.72
Steel
11 - 12.5
6.11 - 6.94
Steel Stainless Austenitic (304)
17.3
9.61
Steel Stainless Austenitic (310)
14.4
8
Steel Stainless Austenitic (316)
16.0
8.89
Steel Stainless Ferritic (410)
9.9
5.5
Strontium
22.5
12.5
Tantalum
6.5
3.61
Tellurium
36.9
20.5
Terbium
10.3
5.72
Terne
11.6
6.44
Thallium
29.9
16.6
Thorium
12
6.67
Thulium
13.3
7.39
Tin
20 - 23
11.1 - 12.8
Titanium
8.5 - 9
4.72 - 5
Topas
5 - 8
2.78 - 4.44
Tungsten
4.5
2.5
Uranium
13.4
7.44
Vanadium
8
4.44
Vinyl Ester
16 - 22
8.89 - 12.2
Vulcanite
63.6
35.3
Wax
2 - 15
1.11 - 8.33
Wedgwood ware
8.9
4.94
Wood, fir
3.7
2.06
Wood, parallel to grain
3
1.67
Wood, across (perpendicular) to grain
30
16.7
Wood, pine
5
2.78
Ytterbium
26.3
14.6
Yttrium
10.6
5.89
Zinc
30 - 35
16.7 - 19.4
Zirconium
5.7
3.17
m/m = meter per meter, in/in = inches per inches
Most values for temperature 25 C (77 F). The span in the values may be caused by the variation in the materials themselves - or by the variation in the sources used



  • tK = tC + 273.16
  • tR = tF + 459.67 
  • 1 in (inch) = 25.4 mm
  • 1 ft (foot) = 0.3048 m
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